Diisopropanolamine (DIPA)
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Category:
Amine Derivatives
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Product Profile
1. Chemical Structure and Properties
Molecular Formula: C6H15NO2
Structural Formula: (CH3)2CHOH–CH2–NH–CH2–CH(OH)CH3
Physical Properties:
Appearance: Colorless to pale yellow viscous liquid
Boiling Point: Approximately 215-220°C (at 760 mmHg)
Density: About 0.97 g/cm³ at 20°C
Solubility: Miscible with water, alcohols, and many organic solvents
Chemical Properties:
Acts as a tertiary amine with two hydroxyl groups, offering both basicity and polarity
Can neutralize acids and act as a buffering agent
Stable under normal conditions but reactive with strong oxidizers
Flash point: Around 100°C (closed cup) — combustible but less volatile than low molecular weight amines
2. Industrial Applications
Neutralizing Agent:
Widely used in gas treatment processes, especially for removing acidic gases like CO2 and H2S in natural gas and refinery industries.
Corrosion Inhibitor:
Added to boiler water and cooling systems to prevent corrosion by neutralizing acidic impurities.
Chemical Intermediate:
Used as an intermediate in manufacturing emulsifiers, surfactants, and other specialty chemicals.
Textile and Leather Processing:
Acts as a buffering agent and pH adjuster in textile dyeing and leather processing industries.
Agriculture:
Used in the production of herbicides and pesticides formulations.
3. Safety and Toxicology
Health Hazards:
Skin/Eye Contact: May cause irritation or allergic reactions; prolonged exposure can cause dermatitis.
Inhalation: Vapors or mists can irritate the respiratory tract.
Ingestion: Harmful if swallowed; may cause nausea or gastrointestinal upset.
Fire & Explosion Risk:
Combustible liquid; avoid open flames and sources of ignition.
Protective Measures:
Use nitrile gloves, chemical-resistant goggles, and appropriate respiratory protection when handling.
In case of contact, rinse thoroughly with water and seek medical advice if irritation persists.
4. Environmental and Regulatory Considerations
Environmental Impact:
Biodegradable under aerobic conditions, reducing long-term environmental risk.
Toxicity to aquatic life is moderate; avoid release into waterways.
Regulatory Compliance:
Registered under REACH in the EU and listed on TSCA in the USA.
Classified for transport as UN 2924, Class 8 (corrosive substances), Packing Group III.
5. Case Studies: Application Insights
Gas Sweetening:
Successfully employed in natural gas processing plants to capture CO2 and H2S, improving fuel quality and reducing emissions.
Corrosion Control:
Incorporated in boiler water treatment at power plants, leading to prolonged equipment life and reduced maintenance costs.
Comparison with Alternatives:
Compared to monoethanolamine (MEA), DIPA offers lower volatility and better thermal stability, making it favorable in harsh industrial environments.
Offers a balance between performance and safety, especially in corrosion inhibition.